1)           Troyansky, E. I.; Demchuk, D. V.; Ismagilov, R. F.; Lazareva, M. I.; Strelenko, Y. A.; Nikishin, G. I. "Homolytic Macrocyclization of Alkynes with Propane-1,3-Dithiol as a Route to 14-Membered and 21-Membered Crown Thioethers", Mendeleev Commun. 1993, 112-114.

2)           Demchuk, D. V.; Lazareva, M. I.; Lindeman, S. V.; Khrustalyov, V. N.; Struchkov, Y. T.; Ismagilov, R. F.; Troyansky, E. I.; Nikishin, G. I. "Synthesis of 12-Membered and 13-Membered Sulfur-Containing Lactones by Homolytic Macrocyclization of Mercaptoacetic Esters with Alkynes", Synthesis 1995, 307-311.

3)           Troyansky, E. I.; Ismagilov, R. F.; Samoshin, V. V.; Strelenko, Y. A.; Demchuk, D. V.; Nikishin, G. I.; Lindeman, S. V.; Khrustalyov, V. N.; Struchkov, Y. T. "Stereoselective Free-Radical Cycloaddition-Macrocyclization in Facile Synthesis of Trans-Cyclohexano-Fused 12-Membered Crown Thioethers", Tetrahedron 1995, 51, 11431-11444.

4)           Troyansky, E. I.; Ismagilov, R. F.; Strelenko, Y. A.; Samoshin, V. V.; Demchuk, D. V.; Nikishin, G. I.; Lindeman, S. V.; Khrustalyov, V. V.; Struchkov, Y. T. "Remote Asymmetric Induction in Free-Radical Cycloaddition Leading to Trans-Cyclohexano-Fused 12-Membered Crown Thioethers", Tetrahedron Lett. 1995, 36, 2293-2294.

5)           Troyansky, E.; Ismagilov, R. F.; Korneeva, E. N.; Pogosyan, M. S.; Nikishin, G. I. "An Approach to 8-Membered, 16-Membered and 24-Membered Sulfur- Containing Heterocycles Via Homolytic Cycloaddition of Alkynes with Butane-1,4-Dithiol", Mendeleev Commun. 1995, 18-20.

6)           Nelsen, S. F.; Ismagilov, R. F.; Powell, D. R. "Charge localization in a dihydrazine analogue of tetramethyl-p- phenylenediamine radical cation", J. Am. Chem. Soc. 1996, 118, 6313-6314.

7)           Nelsen, S. F.; Ismagilov, R. F.; Chen, L. J.; Brandt, J. L.; Chen, X.; Pladziewicz, J. R. "Slow electron transfer reactions involving tetraisopropylhydrazine", J. Am. Chem. Soc. 1996, 118, 1555-1556.

8)           Nelsen, S. F.; Ismagilov, R. F.; Powell, D. R. "Charge-localized p-phenylenedihydrazine radical cations: ESR and optical studies of intramolecular electron transfer rates", J. Am. Chem. Soc. 1997, 119, 10213-10222.

9)           Nelsen, S. F.; Klein, S. J.; Trieber, D. A.; Ismagilov, R. F.; Powell, D. R. "sigma,pi Interaction in halogen-substituted biadamantylidene radical cations", J. Org. Chem. 1997, 62, 6539-6546.

10)       Nelsen, S. F.; Ramm, M. T.; Ismagilov, R. F.; Nagy, M. A.; Trieber, D. A.; Powell, D. R.; Chen, X.; Gengler, J. J.; Qu, Q. L.; Brandt, J. L.; Pladziewicz, J. R. "Estimation of self-exchange electron transfer rate constants for organic compounds from stopped-flow studies", J. Am. Chem. Soc. 1997, 119, 5900-5907.

11)       Troyansky, E. I.; Ismagilov, R. F.; Samoshin, V. V. "Homolytic cycloaddition of dithiols to alkynes leading to sulfur-containing heterocycles and crown thioethers: new comments to the mechanism." Sulfur Letters 1997, 20, 219.

12)       Nelsen, S. F.; Ismagilov, R. F.; Trieber, D. A. "Adiabatic electron transfer: Comparison of modified theory with experiment", Science 1997, 278, 846-849.

13)       Ismagilov, R. F. "Mathematical description of kinetic resolution with an enantiomerically impure catalyst and nonracemic substrate", J. Org. Chem. 1998, 63, 3772-3774.

14)       Nelsen, S. F.; Ismagilov, R. F.; Gentile, K. E.; Nagy, M. A.; Tran, H. Q.; Qu, Q. L.; Halfen, D. T.; Odegard, A. L.; Pladziewicz, J. R. "Indirect determination of self-exchange electron transfer rate constants", J. Am. Chem. Soc. 1998, 120, 8230-8240.

15)       Nelsen, S. F.; Tran, H. Q.; Ismagilov, R. F.; Ramm, M. T.; Chen, L. J.; Powell, D. R. "Structural information from hydrazine radical cation optical absorption spectra", J. Org. Chem. 1998, 63, 2536-2543.

16)       Nelsen, S. F.; Ismagilov, R. F.; Teki, Y. "Comparison of the singlet, triplet energy gap of a symmetrical diradical dication with ET parameters derived from its optical spectrum", J. Am. Chem. Soc. 1998, 120, 2200-2201.

17)       Nelsen, S. F.; Ismagilov, R. F.; Powell, D. R. "Effects of bridge redox state levels on the electron transfer and optical properties of intervalence compounds with hydrazine charge-bearing units", J. Am. Chem. Soc. 1998, 120, 1924-1925.

18)       Samoshin, V. V.; Troyansky, E. I.; Demchuk, D. V.; Ismagilov, R. F.; Chertkov, V. A.; Lindeman, S. V.; Khrustalyov, V. N.; Struchkov, Y. T. "Conformational analysis of a 12-membered crown dithioether in the solid state and in solution", J. Phys. Org. Chem. 1998, 11, 241-253.

19)       Nelsen, S. F.; Ismagilov, R. F.; Gentile, K. E.; Powell, D. R. "Temperature effects on electron transfer within intervalence bis(hydrazine) radical cations", J. Am. Chem. Soc. 1999, 121, 7108-7114.

20)       Nelsen, S. F.; Ismagilov, R. F. "Ion pairing effects on bis(hydrazine) intervalence radical cations", J. Phys. Chem. A 1999, 103, 5373-5378.

21)       Teki, Y.; Ismagilov, R. F.; Nelsen, S. F. "Intra- and inter-molecular exchange on symmetrical hydrazine diradical dications and comparison of the magnetic exchange with ET parameters derived from their optical spectra", Mol. Cryst. Liq. Cryst. Sci. Technol. Sect. A-Mol. Cryst. Liq. Cryst. 1999, 334, 313-322.

22)       Kenis, P. J. A.; Ismagilov, R. F.; Whitesides, G. M. "Microfabrication inside capillaries using multiphase laminar flow patterning", Science 1999, 285, 83-85.

23)       Takayama, S.; McDonald, J. C.; Ostuni, E.; Liang, M. N.; Kenis, P. J. A.; Ismagilov, R. F.; Whitesides, G. M. "Patterning cells and their environments using multiple laminar fluid flows in capillary networks", Proc. Natl. Acad. Sci. U. S. A. 1999, 96, 5545-5548.

24)       Whitesides, G. M.; Ismagilov, R. F. "Complexity in chemistry", Science 1999, 284, 89-92.

25)       Deng, T.; Arias, F.; Ismagilov, R. F.; Kenis, P. J. A.; Whitesides, G. M. "Fabrication of metallic microstructures using exposed, developed silver halide-based photographic film", Anal. Chem. 2000, 72, 645-651.

26)       Hong, S. H.; Evans, D. H.; Nelsen, S. F.; Ismagilov, R. F. "Evidence for a two-step electron-transfer process in the electrode reactions of tetraisopropylhydrazine, tetracyclohexylhydrazine and their radical cation salts", J. Electroanal. Chem. 2000, 486, 75-84.

27)       Holmlin, R. E.; Ismagilov, R. F.; Haag, R.; Mujica, V.; Ratner, M. A.; Rampi, M. A.; Whitesides, G. M. "Correlating electron transport and molecular structure in organic thin films", Angew. Chem.-Int. Edit. 2001, 40, 2316.

28)       Holmlin, R. E.; Haag, R.; Chabinyc, M. L.; Ismagilov, R. F.; Cohen, A. E.; Terfort, A.; Rampi, M. A.; Whitesides, G. M. "Electron transport through thin organic films in metal- insulator-metal junctions based on self-assembled monolayers", J. Am. Chem. Soc. 2001, 123, 5075-5085.

29)       Nelsen, S. F.; Trieber, D. A.; Ismagilov, R. F.; Teki, Y. "Solvent effects on charge transfer bands of nitrogen-centered intervalence compounds", J. Am. Chem. Soc. 2001, 123, 5684-5694.

30)       Ismagilov, R. F.; Stroock, A. D.; Kenis, P. J. A.; Whitesides, G.; Stone, H. A. "Experimental and theoretical scaling laws for transverse diffusive broadening in two-phase laminar flows in microchannels", Appl. Phys. Lett. 2000, 76, 2376-2378.

31)       Stroock, A. D.; Weck, M.; Chiu, D. T.; Huck, W. T. S.; Kenis, P. J. A.; Ismagilov, R. F.; Whitesides, G. M. "Patterning electro-osmotic flow with patterned surface charge", Phys. Rev. Lett. 2000, 84, 3314-3317.

32)       Kenis, P. J. A.; Ismagilov, R. F.; Takayama, S.; Whitesides, G. M.; Li, S. L.; White, H. S. "Fabrication inside microchannels using fluid flow", Accounts Chem. Res. 2000, 33, 841-847.

33)       Ismagilov, R. F.; Ng, J. M. K.; Kenis, P. J. A.; Whitesides, G. M. "Microfluidic arrays of fluid-fluid diffusional contacts as detection elements and combinatorial tools", Anal. Chem. 2001, 73, 5207-5213.

34)       Ismagilov, R. F.; Rosmarin, D.; Kenis, P. J. A.; Chiu, D. T.; Zhang, W.; Stone, H. A.; Whitesides, G. M. "Pressure-driven laminar flow in tangential microchannels: an elastomeric microfluidic switch", Anal. Chem. 2001, 73, 4682-4687.

35)       Ismagilov, R. F.; Rosmarin, D.; Gracias, D. H.; Stroock, A. D.; Whitesides, G. M. "Competition of intrinsic and topographically imposed patterns in Benard-Marangoni convection", Appl. Phys. Lett. 2001, 79, 439-441.

36)       Ismagilov, R. F.; Schwartz, A.; Bowden, N.; Whitesides, G. M. "Autonomous movement and self-assembly", Angew. Chem.-Int. Edit. 2002, 41, 652.

37)       Stroock, A. D.; Ismagilov, R. F.; Stone, H. A.; Whitesides, G. M. "Fluidic ratchet based on Marangoni-Benard convection", Langmuir 2003, 19, 4358-4362.

38)       Chabinyc, M.L.; Holmin, R.E.; Haag, R.; Chen, X.X.; Ismagilov, R.F.; Rampi, M.A.; Whitesides, G.M.; In Molecules as Components of Electronic Devices Amer. Chem.Soc.: Washington, 2003; Vol. 844, pp 16-35.

_________________________________________________________________________________

39)       Song, H; Tice, J. D.; Ismagilov, R. F. “A Microfluidic System for Controlling Reaction Networks in Time”, Angew. Chem.-Int. Edit. 2003, 768.

40)       Tice, J. D.; Song, H.; Lyon, A. D.; Ismagilov, R. F. "Formation of Droplets and Mixing in Multiphase Microfluidics at Low Values of the Reynolds and Capillary Numbers", Langmuir 2003, 19, 9127-9133.

41)       Ismagilov, R. F. “Integrated Microfluidic Systems”, Angew. Chem.-Int. Edit. 2003, 42, 4130-4132.

42)       Zheng, B.; Roach, L. S.; Ismagilov, R. F. "Screening of Protein Crystallization Conditions on a Microfluidic Chip Using Nanoliter-size Droplets", J. Am. Chem. Soc. 2003, 125, 11170-11171.

43)       Song, H.; Bringer, M. R.; Tice, J. D.; Gerdts, C. J.; Ismagilov, R. F. "Experimental Test of Scaling of Mixing by Chaotic Advection", Appl. Phys. Lett., 2003, 83, 4664-4666.  

44)       Song, H.; Ismagilov, R. F. "Millisecond Kinetics on a Microfluidic Chip Using Nanoliters of Reagents". J. Am. Chem. Soc. 2003, 125, 14613-14619

45)       Tice, J. D.; Lyon, A. D.; Ismagilov, R. F. "Formation and Mixing of Viscous Reagents in Droplets Moving Through Microfluidic Channels",  Anal. Chim. Acta, 2004, 507, 73-77. (invited).

46)     Runyon M. K.; Johnson-Kerner B. L.; Ismagilov R. F  "Minimal Functional Model of Hemostasis in a Biomimetic Microfluidic System", Angew. Chem. Int. Edit. 2004, 43, 1541-1536

47)       Bringer, M. R.; Gerdts, C. J.; Song, H.; Tice, J. D.; Ismagilov, R. F.  "Microfluidic Systems for Chemical Kinetics that Rely on Chaotic Mixing in Droplets", Philos. T. Roy. Soc. A. 2004, 362, 1087-1104.

48)      Zheng, B.; Tice, J. D.; Spencer, L. S.; Ismagilov, R. F.  "A Droplet-Based, Composite PDMS/Glass Capillary Microfluidic System for Evaluating Protein Crystallization Conditions by Microbatch and Vapor-Diffusion Methods with On-Chip X-Ray Diffraction", 2004, 43, 2508-2511.

49)     Gerdts, C. J.; Sharoyan, D. E.; Ismagilov, R. F.  "A Synthetic Reaction Network: Chemical Amplification Using Nonequilibrium Autocatalytic Reactions Coupled in Time", J. Am. Chem. Soc. 2004, 126, 6327-6331.

50)        Shestopalov, I. A.; Tice J. D.; Ismagilov, R. F.  "Multi-Step Chemical Reactions Performed On Millisecond Time Scale In a Microfluidic Droplet-Based System", Lab on a Chip 2004, 4, 316-321.

51)        Zheng, B.; Tice, J. D.; Ismagilov, R. F.  "Formation of Droplets of Alternating Composition in Microfluidic Channels and Applications to Indexing of Concentrations in Droplet-Based Assays", Anal. Chem.  2004,  76, 4977-4982.

52)        Zheng, B.; Tice, J. D.; Ismagilov, R. F.  "Formation of Arrayed Droplets by Soft Lithography and Two-Phase Fluid Flow, and Application in Protein Crystallization", Adv. Mater. 2004 16:1365-1368.

53)       L. Spencer Roach, Helen Song, and Rustem F. Ismagilov,  "Controlling Nonspecific Protein Adsorption in a Plug-Based Microfluidic System by Controlling Interfacial Chemistry Using Fluorous-Phase Surfactants", Anal. Chem. 2005 77 (3): 785-796.

54)        Zheng, B.; Ismagilov, R. F.  "A Microfluidic Approach for Screening Submicroliter Volumes Against Multiple Reagents by Using Preformed Arrays of Nanoliter Plugs in a Three-Phase Liquid/Liquid/Gas Flow", Angew. Chem. Int. Ed. 2005 117: 2576-2579

55)        Lucchetta, E. M.; Lee J. H.; Fu, L. A.; Patel, N. H.; Ismagilov R. F. "Dynamics of Drosophila Embryonic Patterning Network Perturbed in Space and Time with Microfluidics", Nature 2005 434: 1134-1138.

56)       Jing Su, Michelle R. Bringer, Rustem F. Ismagilov, and Milan Mrksich, "Combining Microfluidic Networks and Peptide Arrays for Multi-Enzyme Assays", J. Am. Chem. Soc. 2005 127: 7280-7281

57)       Delai L. Chen, Cory J. Gerdts, and Rustem F. Ismagilov, "Using Microfluidics to Observe the Effect of Mixing on Nucleation of Protein Crystals", J. Am. Chem. Soc. 2005 127: 9672-9673

58)       Maneesh K. Yadav, Cory J. Gerdts, Ruslan Sanishvili, Ward W. Smith, L. Spencer Roach, Rustem F. Ismagilov, Peter Kuhn and Raymond C. Stevens, "In Situ Data Collection and Structure Refinement from Microcapillary Protein Crystallization", Journal of Applied Crystallography 2005 38: 900-905

59)       Bo Zheng, Cory J Gerdts and Rustem F Ismagilov, "Using nanoliter plugs in microfluidics to facilitate and understand protein crystallization", Current Opinion in Structural Biology 2005 15: 548–555

60)        Nelsen,S.F.; Konradsson, A.E.; Ismagilov, R.F. Guzei, I.A., "Crystallographic characterization of the geometry changes upon electron loss from 2-tert-butyl-3-aryl-2,3-diazabicyclo2.2.2. octanes", Cryst. Growth Des. 2005 5: 2344-2347

61)        Elena M. Lucchetta, Matthew S. Munson and Rustem F. Ismagilov, "Characterization of the Local Temperature in Space and Time around a Developing Drosophila Embryo in a Microfluidic Device", Lab on a Chip 2006 6: 185-190

62)       Takuji Hatakeyama, Delai L. Chen and Rustem F. Ismagilov, "Microgram-Scale Testing of Reaction Conditions in Solution Using Nanoliter Plugs in Microfluidics with Detection by MALDI-MS", J.Am.Chem.Soc. 2006 128: 2518-2519

63)       Delai L. Chen and Rustem F. Ismagilov, "Microfluidic Cartridges Preloaded with Nanoliter Plugs of Reagents: an Alternative to 96-well Plates for Screening", COCB 2006 10: 226-231

64)        Helen Song, Hung-Wing Li, Matthew S. Munson, Thuong G. Van Ha and Rustem F. Ismagilov, "On-chip Titration of an Anticoagulant Argatroban and Determination of the Activated Partial Thromboplastin Time for Clotting within Whole Blood or Plasma Using a Plug-based Microfluidic System", Anal. Chem. 2006 78: 4839-4849

65)       David N.Adamson, Debarshi Mustafi, John X.J.Zhang, Bo Zheng and Rustem F. Ismagilov, "Production of arrays of chemically distinct nanolitre plugs via repeated splitting in microfluidic devices", Lab on a Chip, 2006 6: 1178- 1186

66)       Christian J. Kastrup, Matthew K. Runyon, Feng Shen, and Rustem F. Ismagilov, "Modular chemical mechanism predicts spatiotemporal dynamics of initiation in the complex network of hemostasis", PNAS 2006 103:15747-15752

67)       Helen Song, Delai L. Chen, and Rustem F. Ismagilov, "Reactions in droplets in microfluidic channels", Angew. Chem. Int. Ed. 2006 45:7336-7356

69)       Liang Li, Debarshi Mustafi, Qiang Fu, Valentina Tereshko, Delai L. Chen, Joshua D. Tice, and Rustem F. Ismagilov, "Nanoliter microfluidic hybrid method for simultaneous screening and optimization validated with crystallization of membrane proteins", PNAS 2006 103: 19243-19248

70)      Delai L. Chen, Liang Li, Sebastian Reyes, David N. Adamson, and Rustem F. Ismagilov, "Using Three-Phase Flow of Immiscible Liquids To Prevent Coalescence of Droplets in Microfluidic Channels: Criteria To Identify the Third Liquid and Validation with Protein Crystallizations", Langmuir 2007 23: 2255-2260

71)       Liang Li, James Q. Boedicker, and Rustem F. Ismagilov, "Using a Multijunction Microfluidic Device To Inject Substrate into an Array of Preformed Plugs without Cross-Contamination: Comparing Theory and Experiments", Anal. Chem. 2007 79: 2756-2761

72)       Christian J. Kastrup, Feng Sheng, and Rustem F.Ismagilov, "Response to Shape Emerges in a Complex Biochemical Network and Its Simple Chemical Analogue", Angew. Chem. Int. Ed. 200746: 3660-3662

73)      Matthew K. Runyon, Bethany L. Johnson-Kerner, Christian J. Kastrup, Thuong G. Van Ha, and Rustem F.Ismagilov, "Propagation of Blood Clotting in the Complex Biochemical Network of Hemostasis Is Described by a Simple Mechanism", JACS 2007 129: 7014-7015

74)      Christian J. Kastrup, and Rustem F.Ismagilov, "A physical organic mechanistic approach to understanding the complex reaction network of hemostasis (blood clotting)", J. Phys. Org. Chem. 2007 20:711-715

75)      Christian J. Kastrup, Feng Shen, Matthew K. Runyon, and Rustem F.Ismagilov, "Characterization of the Threshold Response of Initiation of Blood Clotting to Stimulus Patch Size", Biophysical Journal 2007 93:2969-2977

76)      Petty, R. T.; Li, H.-W.; Maduram, J. H.; Ismagilov, R.; and Mrksich, M., "Attachment of Cells to Islands Presenting Gradients of Adhesion Ligands", J. Am. Chem. Soc. 2007 129: 8966-8967

77)      Ismagilov, R.; and Maharbiz, M, "Can we build synthetic, multicellular systems by controlling developmental signaling in space and time?", Current Opinion in Chemical Biology 2007 11: 604-611

78)     Christian J. Kastrup, Matthew K. Runyon, Elena M. Lucchetta, Jessica M. Price, and Rustem F. Ismagilov, “Using Chemistry and Microfluidics to Understand the Spatial Dynamics of Complex Biological Networks”, Acc. Chem. Res. 2008 41:449-558

79)      Matthew K. Runyon, Christian J. Kastrup,Bethany L. Johnson-Kerner, Thuong G, Van Ha, and Rustem F. Ismagilov, "Effects of Shear Rate on Propagation of Blood Clotting Determined Using Microfluidics and Numerical Simulations”, JACS 2008 130: 3458-3464

80)      Rebecca R. Pompano, Hung-Wing Li, and Rustem F. Ismagilov, "Rate of mixing controls rate and outcome of autocatalytic processes—theory and microfluidic experiments with chemical reactions and blood coagulation”, Biophysical Journal 2008 early edition